Let's try posting in a more appropriate forum next time. This one is for suggestions and feedback about our site so I'll move this one. Multiposting isn't allowed either - you posted this same question twice. In answer to your question if you have either PowerDVD or WinDVD you should be able to pause the film then capture the screenshot. After that you can print it out but don't expect good resolution.
Sorry for the mistake, I did not really know what I was doing because this forum thing is new to me. But thank you for your answer and moving my posting to the right place.